Abstract
In the past few years, graphene-based nanocomposites are a hot topic in the fields of materials and chemistry owing to their unique features. We describe a facile melt blending method for preparing polypropylene/graphene nanocomposites in this article. The first stage involved grafting graphene onto chlorinated PP using the Friedel–Crafts reaction. The second stage involved the use of the resulting PP grafted graphene (PPG) as fillers in a melt blend with commercial PP. After being grafted with an organic PP chain, graphene becomes lipophilic; consequently, the PPG can be dispersed well within the PP matrix while retaining excellent interface adhesion. As a result, the thermostability, mechanical performance, and electrical conductivity of PP were significantly improved through the addition of PPG fillers. Additionally, with 10 wt% of PPG fillers (equivalent to 5 wt% graphene sheets), the conductivity approaches 6.8 S m−1. As a result of this research, a new method for producing high-performance PP has been developed. Graphical Abstract: [Figure not available: see fulltext.].
| Original language | English |
|---|---|
| Pages (from-to) | 1156-1163 |
| Number of pages | 8 |
| Journal | Journal of Inorganic and Organometallic Polymers and Materials |
| Volume | 33 |
| Issue number | 5 |
| DOIs | |
| State | Published - May 2023 |
Keywords
- Composite materials
- Electrical properties
- Nanocomposites
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Zhang, H. X., Yan, X., Han, W., Liu, C., Chen, Y., Xia, Y. Y., Cai, Z. G., Yoon, K. B., & Yang, J. M. (2023). Fabrication of High-Performance PP/Graphene Nanocomposites via Friedel–Crafts. Journal of Inorganic and Organometallic Polymers and Materials, 33(5), 1156-1163. https://doi.org/10.1007/s10904-023-02567-2
Zhang, He xin ; Yan, Xin ; Han, Wei et al. / Fabrication of High-Performance PP/Graphene Nanocomposites via Friedel–Crafts. In: Journal of Inorganic and Organometallic Polymers and Materials. 2023 ; Vol. 33, No. 5. pp. 1156-1163.
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title = "Fabrication of High-Performance PP/Graphene Nanocomposites via Friedel–Crafts",
abstract = "In the past few years, graphene-based nanocomposites are a hot topic in the fields of materials and chemistry owing to their unique features. We describe a facile melt blending method for preparing polypropylene/graphene nanocomposites in this article. The first stage involved grafting graphene onto chlorinated PP using the Friedel–Crafts reaction. The second stage involved the use of the resulting PP grafted graphene (PPG) as fillers in a melt blend with commercial PP. After being grafted with an organic PP chain, graphene becomes lipophilic; consequently, the PPG can be dispersed well within the PP matrix while retaining excellent interface adhesion. As a result, the thermostability, mechanical performance, and electrical conductivity of PP were significantly improved through the addition of PPG fillers. Additionally, with 10 wt% of PPG fillers (equivalent to 5 wt% graphene sheets), the conductivity approaches 6.8 S m−1. As a result of this research, a new method for producing high-performance PP has been developed. Graphical Abstract: [Figure not available: see fulltext.].",
keywords = "Composite materials, Electrical properties, Nanocomposites",
author = "Zhang, {He xin} and Xin Yan and Wei Han and Chen Liu and Yujian Chen and Xia, {You yi} and Cai, {Zheng guo} and Yoon, {Keun Byoung} and Yang, {Jian ming}",
note = "Publisher Copyright: {\textcopyright} 2023, The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature.",
year = "2023",
month = may,
doi = "10.1007/s10904-023-02567-2",
language = "English",
volume = "33",
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Zhang, HX, Yan, X, Han, W, Liu, C, Chen, Y, Xia, YY, Cai, ZG, Yoon, KB & Yang, JM 2023, 'Fabrication of High-Performance PP/Graphene Nanocomposites via Friedel–Crafts', Journal of Inorganic and Organometallic Polymers and Materials, vol. 33, no. 5, pp. 1156-1163. https://doi.org/10.1007/s10904-023-02567-2
Fabrication of High-Performance PP/Graphene Nanocomposites via Friedel–Crafts. / Zhang, He xin; Yan, Xin; Han, Wei et al.
In: Journal of Inorganic and Organometallic Polymers and Materials, Vol. 33, No. 5, 05.2023, p. 1156-1163.
Research output: Contribution to journal › Article › peer-review
TY - JOUR
T1 - Fabrication of High-Performance PP/Graphene Nanocomposites via Friedel–Crafts
AU - Zhang, He xin
AU - Yan, Xin
AU - Han, Wei
AU - Liu, Chen
AU - Chen, Yujian
AU - Xia, You yi
AU - Cai, Zheng guo
AU - Yoon, Keun Byoung
AU - Yang, Jian ming
N1 - Publisher Copyright:© 2023, The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature.
PY - 2023/5
Y1 - 2023/5
N2 - In the past few years, graphene-based nanocomposites are a hot topic in the fields of materials and chemistry owing to their unique features. We describe a facile melt blending method for preparing polypropylene/graphene nanocomposites in this article. The first stage involved grafting graphene onto chlorinated PP using the Friedel–Crafts reaction. The second stage involved the use of the resulting PP grafted graphene (PPG) as fillers in a melt blend with commercial PP. After being grafted with an organic PP chain, graphene becomes lipophilic; consequently, the PPG can be dispersed well within the PP matrix while retaining excellent interface adhesion. As a result, the thermostability, mechanical performance, and electrical conductivity of PP were significantly improved through the addition of PPG fillers. Additionally, with 10 wt% of PPG fillers (equivalent to 5 wt% graphene sheets), the conductivity approaches 6.8 S m−1. As a result of this research, a new method for producing high-performance PP has been developed. Graphical Abstract: [Figure not available: see fulltext.].
AB - In the past few years, graphene-based nanocomposites are a hot topic in the fields of materials and chemistry owing to their unique features. We describe a facile melt blending method for preparing polypropylene/graphene nanocomposites in this article. The first stage involved grafting graphene onto chlorinated PP using the Friedel–Crafts reaction. The second stage involved the use of the resulting PP grafted graphene (PPG) as fillers in a melt blend with commercial PP. After being grafted with an organic PP chain, graphene becomes lipophilic; consequently, the PPG can be dispersed well within the PP matrix while retaining excellent interface adhesion. As a result, the thermostability, mechanical performance, and electrical conductivity of PP were significantly improved through the addition of PPG fillers. Additionally, with 10 wt% of PPG fillers (equivalent to 5 wt% graphene sheets), the conductivity approaches 6.8 S m−1. As a result of this research, a new method for producing high-performance PP has been developed. Graphical Abstract: [Figure not available: see fulltext.].
KW - Composite materials
KW - Electrical properties
KW - Nanocomposites
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U2 - 10.1007/s10904-023-02567-2
DO - 10.1007/s10904-023-02567-2
M3 - Article
AN - SCOPUS:85147745185
SN - 1574-1443
VL - 33
SP - 1156
EP - 1163
JO - Journal of Inorganic and Organometallic Polymers and Materials
JF - Journal of Inorganic and Organometallic Polymers and Materials
IS - 5
ER -
Zhang HX, Yan X, Han W, Liu C, Chen Y, Xia YY et al. Fabrication of High-Performance PP/Graphene Nanocomposites via Friedel–Crafts. Journal of Inorganic and Organometallic Polymers and Materials. 2023 May;33(5):1156-1163. doi: 10.1007/s10904-023-02567-2
